The site owner may have set restrictions that prevent you from accessing the site. For physicochemical, thermodynamic, transport, spectra, and other property data & information, the followings are available from Mol-Instincts, a chemical database based on quantum chemical computations: The SMILES string of ISOBUTANE is CC(C)C, which can be can be imported by most molecule editors for conversion back into two-dimensional drawings or three-dimensional models of the ISOBUTANE. No tracking or performance measurement cookies were served with this page. ), , 1992, 66-70, In original 66-70. umn class: Semi-standard non-polar; Column length: 20 m; Column type: Packed; CAS no: 75285; Active phase: Apieson L; Substrate: Chromosorb W; Data type: Normal alkane RI; Authors: Kojima, T.; Fujii, T.; Hosaka, Y., Thermal decomposition products of sterepisomeric polypropylenes, Mass Spectrometry, 28(4), 1980, 335-341. ass: Standard non-polar; Column diameter: 0.22 mm; Column length: 80 m; Column type: Capillary; Heat rate: 1 K/min; Start T: 30 C; End T: 130 C; CAS no: 75285; Active phase: OV-101; Carrier gas: N2; Data type: Linear RI; Authors: Yin, C.; Liu, W.; Li, Z.; Pan, Z.; Lin, T.; Zhang, M., Chemometrics to chemical modeling: structural coding in hydrocarbons and retention indices of gas chromatography, J. Sep. For example, we can represent pentane (CH3CH2CH2CH2CH3) and isopentane [(CH3)2CHCH2CH3] as follows: Parentheses in condensed structural formulas indicate that the enclosed grouping of atoms is attached to the adjacent carbon atom. ; Paizanskaya, I.L., Identification of hydrocarbons C1-C9 of petrol fractions of oils and condensates in the use of capillary columns with dinonylphthalate, Zh. Condensed chemical formulas show the hydrogen atoms (or other atoms or groups) right next to the carbon atoms to which they are attached. class: Standard non-polar; Column diameter: 0.2 mm; Column length: 100 m; Column type: Capillary; Description: 5C(10min)=>5C/min=>50C(48min)=>1.5C/min=>195C(91min); CAS no: 75285; Active phase: Petrocol DH-100; Carrier gas: He; Data type: Kovats RI; Authors: Haagen-Smit Laboratory, Procedure for the detailed hydrocarbon analysis of gasolines by single column high efficiency (capillary) column gas chromatography, SOP NO. How many different structural isomers are there for a hydrocarbon with the formula c5h12? This entity has been manually annotated by the ChEBI Team. Chromatogr., 7(2), 1989, 88-92. ass: Standard non-polar; Column type: Capillary; CAS no: 75285; Active phase: Methyl Silicone; Data type: Normal alkane RI; Authors: Chen, Y.; Feng, C., QSPR study on gas chromatography retention index of some organic pollutants, Comput. A molecular formula shows only the kinds and numbers of atoms in a molecule. Accessibility StatementFor more information contact us atinfo@libretexts.orgor check out our status page at https://status.libretexts.org. Longest chain - Propane. Gas Chromatogr., , 1967, 506-510. umn class: Standard polar; Column length: 26 ft; Column type: Packed; Start T: 130 C; CAS no: 75285; Active phase: Carbowax 20M; Substrate: Diatoport P; Data type: Kovats RI; Authors: Widmer, H., Gas chromatographic identification of hydrocarbons using retention indices, J. The condensed formulas show hydrogen atoms right next to the carbon atoms to which they are attached, as illustrated for butane: The ultimate condensed formula is the skeletal formula (sometimes known as a line-angle formula), in which carbon atoms are implied at the corners and ends of lines, and each carbon atom is understood to be attached to enough hydrogen atoms to give each carbon atom four bonds. For example, the molecular formula C4H10 tells us there are 4 carbon atoms and 10 hydrogen atoms in a molecule, but it doesnt distinguish between butane and isobutane. Stars. Please hyperlink Mol-Instincts to www.molinstincts.com. 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Since the molecular formula of Butane is C4H10, the condensed Safety glasses, good ventilation. A molecular formula shows only the kinds and numbers of atoms in a molecule. For example, we can represent pentane (CH3CH2CH2CH2CH3) and isopentane [(CH3)2CHCH2CH3] as follows: Parentheses in condensed structural formulas indicate that the enclosed grouping of atoms is attached to the adjacent carbon atom. Constitutional Isomers, also known as structural isomers, are connected differently and have different bonding sequences. 5. For example, look at the structure of n-butane and isobutane. For example, the molecular formula C 4 H 10 tells us there are 4 carbon atoms and 10 hydrogen atoms in a molecule, but it doesn't distinguish between butane and isobutane. It is a method that uses shorthand notation that contains more information than the chemical formula. Butane has two Isobutane is obtained by isomerization of butane. ; Douglas, L.J. Provide IUPAC name of each molecule you have drawn. Unfortunately, structural formulas are difficult to type/write and take up a lot of space. Chim. ; Kail, S.; Spock, P.S., Linear temperature programmed retention indices of gasoline range hydrocarbons and chlorinated hydrocarbons on cross-linked polydimethylsiloxane, J. Hi. - The structural formula of any compound is different from the . Biology Laboratory. II. Heat of Vaporization at Normal Boiling Point, LogP (Octanol-Water Partition Coefficient), Ghose-Crippen Octanol-Water Partition Coefficient (logP), Moriguchi Octanol-Water Partition Coefficient (logP), Activity Score for Ion Channel Modulators, Activity Score for Nuclear Receptor Ligands, Normal Mode Frequency Analysis with Animation, Molecular Orbital (HOMO & LUMO) Visualization, quantum Chemical Computation Data (20 sets), Structure Data File (SDF/MOL File) of ISOBUTANE, 4-(hydroxyamino)-N-(5-methyl-1,2-oxazol-3-yl)benzene-1-sulfonamide, PROPANE-1,1,1,2,3,3,3-D7,2-(METHYL-D3)- (6CI,7CI,8CI,9CI). bonded to another forming a chain with Hydrogens bonded to each of Formula: C 4 H 10; Molecular weight: 58.1222; IUPAC Standard . Isobutane has the condensed structural formula of CH (CH3)3. Isobutane is also used as a propellant for aerosol spray cans. Chemists often use condensed structural formulas to alleviate these problems. The carbon atoms in the chemical structure of ISOBUTANE are implied to be located at the corner(s) and hydrogen atoms attached to carbon atoms are not indicated each carbon atom is considered to be associated with enough hydrogen atoms to provide the carbon atom with four bonds. The alkyl group with the condensed structural formula (CH3)2CH-is: a. isomethyl b. ethyl. The structural formula for propane shows three axial carbon atoms and eight peripheral hydrogen atoms. Res. For example, the molecular formula C 4 H 10 tells us there are 4 carbon atoms and 10 hydrogen atoms in a molecule, but it doesn't distinguish between butane and isobutane. For example, the molecular formula C4H10 tells us there are 4 carbon atoms and 10 hydrogen atoms in a molecule, but it doesnt distinguish between butane and isobutane. The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. The condensed formulas show hydrogen atoms right next to the carbon atoms to which they are attached, as illustrated for butane: The ultimate condensed formula is a line-angle formula, in which carbon atoms are implied at the corners and ends of lines, and each carbon atom is understood to be attached to enough hydrogen atoms to give each carbon atom four bonds. Isobutane has the condensed structural formula of Thus, structural formulas identify the specific isomers by showing the order of attachment of the various atoms. ChEBI ID. Our objective is to expand the mechanism by introducing the idea of an isobutane graph that has the chemical formula C 4 H 10 and CAS number 75-28-5. That is the most basic tertiary carbon alkane. A substance used in a thermodynamic heat pump cycle or refrigeration cycle that undergoes a phase change from a gas to a liquid and back. An alkane that is propane substituted by a methyl group at position 2. Source: Mol-Instincts Chemical Database, Predicted on Quantum Chemical Computations. Thus, structural formulas identify the specific isomers by showing the order of attachment of the various atoms. ; Paizanskaya, I.L., Identification of hydrocarbons C1-C9 of petrol fractions of oils and condensates in the use of capillary columns with dinonylphthalate, Zh. Draw line-angle formulas given structural formulas. Isobutane. ; Lonneman, W.A., Characterization of non-methane volatile organic compounds at swine facilities in eastern North Carolina, Atm. Isobutane is oxidized to tert-butyl hydroperoxide, which is subsequently reacted with propylene to yield propylene oxide. Draw line-angle formulas given structural formulas. 11.3: Condensed Structural and Line-Angle Formulas is shared under a not declared license and was authored, remixed, and/or curated by LibreTexts. atom in the center of the molecule. For example, the molecular formula C4H10 tells us there are 4 carbon atoms and 10 hydrogen atoms in a molecule, but it doesnt distinguish between butane and isobutane. 6.2: Condensed Structural and Line-Angle Formulas is shared under a CC BY-NC-SA license and was authored, remixed, and/or curated by LibreTexts. May form explosive mixtures with air. The composition of propane can be more compactly expressed as C 3 H 8. ], colourless odourless gas (or colourless cryogenic liquid). [1] Since the longest continuous chain in isobutane contains only three carbon atoms, the preferred IUPAC name is 2-methylpropane but the locant (2-) is typically omitted in general nomenclature as redundant; C2 is the only position on a propane chain where a methyl substituent can be located without altering the main chain and forming the constitutional isomer n-butane. It is also known as i-butane, 2-methylpropane, or methylpropane. Butane, or C4H10, is an alkane natural gas derivative which can be found as two different structural isomers, n-butane or isobutane, or a blend of the two. Chromatogr. It has a role as a non-polar solvent. ), 32(5), 1996, 656-666, In original 656-666. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 100 m; Column type: Capillary; Heat rate: 5 K/min; Start T: 30 C; End T: 310 C; End time: 5 min; CAS no: 75285; Active phase: OV-1; Carrier gas: Helium; Phase thickness: 0.25 um; Data type: Normal alkane RI; Authors: Krkosova, Z.; Kubinec, R.; Addova, G.; Jurdakova, H.; Blasko, J.; Ostrovsky, I.; Sojak, L., Gas chromatographic - mass spectrometric characterization of monomethylalkanes from fuel diesel, Petroleum & Coal, 49(3), 2007, 51-62. class: Standard non-polar; Column diameter: 0.32 mm; Column length: 60 m; Column type: Capillary; Description: -50 0C (2 min) ^ 8 0C/min -> 200 0C (7.75 min) ^ 25 0C -> 225 0C (8 min); CAS no: 75285; Active phase: Methyl Silicone; Carrier gas: Helium; Phase thickness: 1.0 um; Data type: Normal alkane RI; Authors: Blunden, J.; Aneja, V.P. It derives from a hydride of an isobutane. Draw complete structural formula of 2-Bromo-3,4-dimethyloctane. CHEBI:30363. isobutane. The 3D chemical structure image of ISOBUTANE is based on the ball-and-stick model which displays both the three-dimensional position of the atoms and the bonds between them. the molecular formula is C8H10. The process of moving from one open window to another is called what? CSID:6120, http://www.chemspider.com/Chemical-Structure.6120.html (accessed 19:50, Jan 18, 2023), Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agencys EPISuite, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. 2023 ChemEssen, Inc. All rights reserved. bonded to it. Draw a line-angle formula for the compound CH 3 CH 2 CH (CH 3 )CH 2 CH 2 CH 3. Isobutane is used as part of blended fuels, especially common in fuel canisters used for camping.[9]. In this isomer, 3 Carbons are bonded to a single Carbon For example, the condensed formula of butane is CH 3 CH 2 CH 2 CH 3, and that of 2-chloropropane is (CH 3) 2 CHCl. Chem. Gas Chromatogr., , 1967, 506-510. umn class: Semi-standard non-polar; Column diameter: 0.22 mm; Column length: 50 m; Column type: Capillary; Start T: 50 C; CAS no: 75285; Active phase: Squalane; Carrier gas: He; Data type: Kovats RI; Authors: Lunskii, M.Kh. c . ; Flanagan, R.J., Detection and Identification of Volatile Organic Compounds in Blood by Headspace Gas Chromatography as an Aid to the Diagnosis of Solvent Abuse, J. CH(CH3)3. The ISOBUTANE compound may be called differently depending on the various different situations of industrial applications. Instrum. formula is: The condensed structural formula for the compound 1-Octanol is Chem., 27, 2003, 339-353. ass: Standard non-polar; Column type: Capillary; CAS no: 75285; Active phase: Polydimethyl siloxanes; Data type: Normal alkane RI; Authors: Zenkevich, I.G. Molecular Formula: C 4 H 10 O or (CH 3) 2 CHCH 2 OH: Synonyms: 2-Methyl-1-propanol. A molecular formula shows only the kinds and numbers of atoms in a molecule. ; Jacobs, P.A., On-Line Single Run Analysis of Effluents from a Fischer-Tropsch Reactor, J. Chromatogr. What is the condensed structural formula of butane? 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